Search results for "Slurry photocatalytic reactor"

showing 2 items of 2 documents

Guidelines for the Assessment and the Validation of the Rate Law of Slurry Photocatalytic Reactions

2017

The assessment of the rate law of slurry photocatalytic reactions appears to be a hard task, mainly because in this type of reactions the average rate of reaction, which is experimentally observed in a real reactor, could be very different from the “true” (intrinsic) rate of reaction, which cannot be measured directly. In the present work, it is shown how a proper mathematical model allows the utilization of the differential and/or the integral methods of kinetic analysis. The mathematical model must take into account not only the momentum and the mass balances, but also the radiative transfer equation. However, the discrimination among different proposed kinetic laws remains difficult sinc…

Settore ING-IND/24 - Principi Di Ingegneria ChimicaPhotocatalysiSlurry photocatalytic reactorMechanistic kinetic modelLangmuir-Hinshelwood kineticFormic acidSettore CHIM/07 - Fondamenti Chimici Delle TecnologieKinetic analysi
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Guidelines for the assessment of the rate law of slurry photocatalytic reactions

2017

Abstract The assessment of the rate law of slurry photocatalytic reactions appears to be a hard task, mainly because in this type of reactions the average rate of reaction, which is experimentally observed in a real reactor, could be very different from the “true” (intrinsic) rate of reaction, which cannot be measured directly. In the present work, it is shown how a proper mathematical model allows the utilization of the differential and/or the integral methods of kinetic analysis. The mathematical model must take into account not only the momentum and the mass balances, but also the radiative transfer equation. However, the discrimination among different proposed kinetic laws remains diffi…

Work (thermodynamics)Formic acid02 engineering and technology010402 general chemistryKinetic energyKinetic analysi01 natural sciencesCatalysisCatalysiMomentumReaction ratePhotocatalysiRadiative transferOrganic chemistryAbsorption (electromagnetic radiation)ChemistryLangmuir-Hinshelwood kineticChemistry (all)General ChemistryRate equationMechanics021001 nanoscience & nanotechnology0104 chemical sciencesSlurry photocatalytic reactorMechanistic kinetic modelSlurry0210 nano-technology
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